ARSENIC PENTACHLORIDE.
نویسندگان
چکیده
منابع مشابه
Niobium Pentachloride Catalysed Ring Opening of Epoxides
Epoxide ring opening is a frequently required transformation in Organic Synthesis. In this paper we describe the application of NbCl5 for this purpose using three different substrates. Chlorohydrins, 1,2-diols, products containing solvent residues as well as rearrangement products are obtained, depending on both the substrate structure and reaction conditions. Rationalizations to account for so...
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The 1 : 2 molar reactions of MoCl5, in dichloromethane at room temperature, with tetrahydrofuran (thf), tetrahydropyran (thp), dioxane and tetrahydrothiophene (tht) afforded, respectively, [Mo(O)Cl3(thf)]2, 1, and MoCl4(L)2 (L = thp, 2; dioxane, 3; tht, 4), in 81-87% yields. The molecular structures of 1, 2 and 4 were ascertained by X-ray diffractometry. DFT and spectroscopic (IR, NMR) studies ...
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Arsenic (atomic number, 33; relative atomic mass, 74.92) has chemical and physical properties intermediate between a metal and a nonmetal, and is often referred to as a metalloid or semi-metal. It belongs to Group VA of the Periodic Table, and can exist in four oxidation states: –3, 0, +3, and +5. Arsenite, AsIII, and arsenate, AsV, are the predominant oxidation states under, respectively, redu...
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Arsenic, arsenic trioxide and pentoxide, arsenous acids, arsenic acid and their salts (arsenites and arsenates) are carcinogenic substances (Carcinogen category 1) and do not, therefore, have MAK and BAT values (Greim 2002). The former TRK value (technical exposure limit) for arsenic and its inorganic compounds was 0.10 mg arsenic/m (measured as the inhalable fraction of the aerosol; calculated...
متن کاملEfficient one-pot synthesis of 14-aryl-14 -dibenzo[ , ]xanthene derivatives promoted by niobium pentachloride
A simple and efficient procedure for the synthesis of 14-aryl-14H-dibenzo[a,j ]xanthene derivatives through one-pot condensation of 2-naphthol with aryl aldehydes in the presence of niobium pentachloride is described. The reactions were carried out using 25 mole % of NbCl5, at ambient temperature, and in acceptable reaction times, affording excellent yields of the products. c © 2014 Institute o...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 1902
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja02025a008